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Carbon valence electrons7/31/2023 ![]() ![]() What about more complex examples? Carbon (C) has four valence electrons, and requires four additional electrons to have the same valence shell configuration as Neon (Ne). Therefore it appears that there are two electrons in the valence shells of both the red H and the blue H. When the two atoms share their single electrons (shown within the oval), the origins of the electrons are indistinguishable from one another. Shown below, each Hydrogen atom (H) and its single electron are depicted in either red or blue. The simplest way to achieve this is for two hydrogen atoms to share their single electron with one another. Hydrogen has one electron and requires one additional electron to have the same valence shell configuration as the noble gas Helium (He). Let’s first use the example of Hydrogen (H). Therefore atoms that bond covalently share their electrons to complete their valence shell. Electrons can only be so far from an atom before they are no longer associated with it therefore, sharing electrons and forming covalent bonds restricts the maximum distance between two bonded atoms.Ī complete outermost electron shell is the most stable state. In such cases, it is easier to ‘share’ valence electrons.Įlectron ‘sharing’ occurs when the electrons in the outermost electron shell, or valence shell electrons, from one atom can be used to complete the outermost electron shell of another atom without being permanently transferred, as occurs in the formation of an ion. Unlike ionic bonds, covalent bonds are often formed between atoms where one of the atoms cannot easily attain a noble gas electron shell configuration through the loss or gain of one or two electrons. Due to these repulsive forces between the valence shell electron pairs, the CO2 molecule acquires a linear shapeto keep the repulsion at the least.1) Covalent bonds are formed between atoms through simultaneous ‘sharing’ of electrons.Ģ) More than one pair of electrons can be shared between atoms to form double or triple covalent bonds. As a result, there are no lone pairs of electrons, but bonding pairs of electrons also repel each other. Here in CO2, both Oxygen atoms form sigma bonds with the central carbon atom and complete their octet. The molecular Geometry of any compound is based on the arrangement of atoms, electron pairs, and bonds. Remaining electrons in the p-orbitals in the Oxygen atom form pi bonds.Īs sp orbitals are hybridized to form the bonds, CO2 has an sp hybridization. These two hybridized orbitals overlap with the two p-orbitals of the Oxygen atom that results in the formation of sigma bonds. In contrast, the Oxygen atom hybridizes to form three sp2 hybrid orbitals. ![]() Here the 2s orbitals and one of the p-orbitals will hybridize to form 2 sp orbitals. In its excited state, the atom’s electronic configuration becomes 1s2 2s1 2p3, so now every p-orbital of the atoms has one electron each. Total number of valence electrons in the molecule = 16 Valence electrons in Oxygen: 6*2 = 12 ( as there are two Oxygen atoms in the molecule, we will multiply it by 2).To know the bond formation and the arrangement, let’s go through the valence electrons of all the atoms in the molecule. Two Oxygen atoms are located on the terminals where both these atoms share electrons and form bonds with the central Carbon atom. In CO2, the Carbon atom is in the central position as it is the least electronegative atom in the molecule. Now that you know how the Lewis structure is drawn and its uses let us quickly look at the CO2 Lewis structure. Such structure helps in understanding the arrangement of atoms along with the electrons participating in the bond formation. Drawing lines represent the bonds formed in the molecule. ![]() These valence electrons are represented by drawing dots around the individual atoms, hence the Lewis dot structure. Lewis dot structure is a pictorial representation of the arrangement of the valence shell electrons in the molecule. To know the lewis structure of CO2, one should first understand what precisely the Lewis structure is. This structure helps in knowing the arrangement of electrons in the molecules and the shape of the molecule. One needs to know the Lewis structure in order to understand the molecular geometry of any given molecule. Name of molecule Carbon Dioxide ( CO2) No of Valence Electrons in the molecule 16 Hybridization of CO2 sp hybridization Bond Angles 180 degrees Molecular Geometry of CO2 Linear CO2 Lewis Structure ![]() Repetier server work with other slicers7/31/2023 ![]() ![]() ![]() The g-codes are printer specific and can immediately be sent to your 3D printer for manufacturing the prints. Ultimaker Cura slices your models into layers and then creates a list of instructions called g-code. Put those fears to rest because Cura works with several other brands. Knowing that Cura is a pet project of one 3D printer brand, you might be concerned that your 3D printer might not be compatible with the software. ![]() The software assists more than 1.4 million prints a week. According to a 2019 Manufactur3D report, Cura has half a million unique users every month. It was maintained by Ultimaker and its users. Originally developed by David Braam, Cura had its start as open-source software. Ultimaker Cura: Everything You Need to Know Ultimaker Cura has hundreds of printer settings profiles ready for use, whereas Slic3r will require you to source your printer’s profile and import them into the system.Ultimaker Cura allows you to remove supports where they are not needed, whereas Slic3r has yet to include this feature.Ultimaker Cura gives you a lot of model information, whereas Slic3r only tells you the length of the filament used.Ultimaker Cura allows for easy positioning and rotation for your models, whereas Slic3r’s movement icons are quite difficult to master.Ultimaker Cura has two layouts - recommended for beginners and custom for more advanced users, whereas Slic3r uses categories and sub-categories to organize its settings.The Main Differences Between Ultimaker Cura vs Slic3r Main Differences Between Ultimaker Cura vs Slic3r Are there other slicer software out there? What are the things that you should consider when choosing a slicing program? What are slicers and why do you need them? The Slicing Program Showdown: Comparing Slic3r and Ultimaker Cura.What You Would Like About Ultimaker Cura.Ultimaker Cura: Everything You Need to Know.Main Differences Between Ultimaker Cura vs Slic3r. ![]() Gran turismo 7 ps4 gamestop7/31/2023 ![]() ![]() Stay tuned to GamingBolt and we will keep you informed either way. For digital, there’s the standard edition for either PS4 or PS5 and the Digital Deluxe that comes with both. While Gran Turismo Sport came out less than a year ago, Gran Turismo 6 launched five years back all the way back in 2013, so there’s every chance that the next numbered instalment in the series is in the pipeline. There’s a few editions of Gran Turismo 7 you can get. There is always the chance that Sony might indeed end up announcing something at their E3 conference in a month. While it’s entirely possible that GameStop only used the image as a placeholder, since they obviously may not have any material to use for a game that hasn’t even been announced yet, it still seems a little doubtful. We've been busy keeping track of all the best. ![]() It should be noted, though, that some users in the same NeoGAF thread also pointed out that the cover art for Gran Turismo 7 in the image is a replica of fan art that was created around three years ago, so that doesn’t lend this whole thing a lot of credence. The wait for the next instalment in the Gran Turismo franchise is finally over, with Gran Turismo 7 now available on both PlayStation 5 and PS4. These details include the release date for the game – which, allegedly, is April 2019 – and the fact that it will launch with a collector’s edition as well, a package that will include “a real, wearable racing helmet”, with the latter specifically being information that was relayed to the forum user by an employee of the GameStop store in question. A user on NeoGAF recently created a new thread claiming to have seen promotional cover art images for the game (which remains unannounced as of yet), while also claiming that they found some other details as well. Check them out below.Take this rumour with a massive handful of salt, but it looks like the next main instalment in Sony’s racing sim franchise Gran Turismo may have been leaked by GameStop. Gráficamente es inmejorable y tiene un realismo fantástico. Muy recomendado para aquéllos jugadores que buscan un juego para echarle horas, ya que muchas misiones se pueden alargar muchísimo. Preorder any version of Gran Turismo Sport, and you’ll receive a pack that contains these cars:Ī number of retailers are offering exclusive preorder bonuses. Gran turismo 7 es un gran juego para los amantes de los juegos de carreras de coches y los amantes del motor. In the Limited Edition, you’ll get the standard game, as well as the following items:ģ0 PS4 Gran Turismo Sport Themed Avatars - Based on selected Gran Turismo Sport featured vehicles Like many games these days, Gran Turismo Sport is coming out in a Standard Edition and a Limited Edition. We have all the information you need below, so read on. Now is as good a time as any to put in your preorder for Gran Turismo Sport, but before you do, you’ll want to know about the editions and preorder bonuses on offer. The disc will be offered according to your region. The pre-orders will be for the digital version only, offered on the PlayStationStore (PS Store). The official release of the title is scheduled for March 4, 2021. And if you’re into online racing, there will be plenty for you to do, thanks to a robust competitive mode. Pre-orders for Gran Turismo 7 (GT7) will begin on Tuesday, September 21, 2021. Developer Polyphony Digital is promising a wealth of cars, tracks, and modes to appeal to racing fans of all stripes. Its physics model is accurate, and while the racing can be formulaic it's always a giggle. Set to release sometime in 2017 is the seventh main game in the series, Gran Turismo Sport, a PlayStation 4 exclusive that has yet to get a specific release date. Gran Turismo 7 isn't a departure, but rather a newer, shinier GT game. It’s serious, sensible, structured, and unlike Sony’s previous first-party racing game, DriveClub it’s been. Gran Turismo has been PlayStation’s premier racing series ever since the first installment launched in 1997. Gran Turismo Sport is a very well-crafted online racing destination. ![]() Pdf book of demons and their signs7/30/2023 ![]() ![]() It is therefore conceivable that he may hide behind the facade of a psychosis. It should be noted, however, that Satan does not like to be revealed. Of course professional diagnosis must be made to determine the potential causes of certain behaviors which may be indicative of, for example, schizophrenia, multiple personality disorders or other mental illnesses described in the Diagnostic and Statistical Manual of Mental Disorders IV. In a discussion of the demonic, it is important to be sure that certain psychological disturbances, whether chemically caused or due to an imbalance from emotional distress or trauma, be ruled out before demonic possession is considered. This is commonly known as possession" (Aquinas, p. He does so by inciting a man to cogitate about a particular thing and impedes the use of reason. By its very nature "a demon intends to lead men to falsehood. The demon, he says, "creeps stealthily in through all the avenues of the senses, it gives itself shapes, it adapts itself to colors, it adheres to sounds, it appends itself to odors, it instills with flavors" (Aquinas, p. Augustine, can change the cognitive part of the person by changing his internal and external sensory powers. Moreover, a demon's influence, according to St. Though there are many demons, they describe themselves as legion in Mark's Gospel 5:10, "since there are many of us," they are all in effect minions of Satan who desired to rule like God over a multitude of angels (Aquinas, p. ![]() ![]() For example, in Ephesians 6:12, the Apostle says, "For our wrestling is not against flesh and blood, but against principalities and powers, against the rulers of this world of darkness, against the spirits of wickedness in the high places." Also vital to the description of a demon is that the demon by a free will act turned from good, the natural state of God's creation of which the demon is a part, to embrace evil (Aquinas, p. Saint Paul, for example, continually refers to the demonic forces present in the world and the damage they cause. Aiding reason, faith provides another vantage point for validating the activity of the spirit world. ![]() Surely, this description does not sit well with modern people since it presumes metaphysics which uses reason to know things that are not immediately available to the senses. Traditionally demons have been described as beings without bodies that possess intellect and free will (Aquinas, p. Finally, I will attempt to provide indications of demonic possession and the effects of demonic activity. After having done so I will illustrate / explain misidentification of demonic possession as mental illness or simply the free will actions of a bad person. In my discussion of demons, it is first necessary to define what a demon is and how it acts. The reality of demonic spirits is also well documented in non-Christian religions, notably Judaism, Islam, Buddhism, Hinduism and Tao (Cramer, M., The Devil Within, 1979, p. The topic is also discussed by pagan philosophers as well as in the writing of the doctors of the Church (Aquinas, On Evil, pp. The Gospels are filled with stories of Jesus' encounter with demons. As a matter of fact, I would be displaying great hubris to entertain such doubts. However, now with more than 30 years of priestly experience under my belt and some growth in the Spirit's gift of knowledge infused through the sacraments of Confirmation and Holy Orders, I no longer doubt the reality of malevolent spirits. Though I was aware that the teachings about demons, prayers to ward off the evil spirits and the official rite of exorcism have long been part of the official teaching of the Church, I doubted a modern priest could take such a pre-Enlightenment topic seriously. Earlier in my priesthood, I would not have been able to write this article and I certainly would have looked askance at anyone who broached the topic of demonology. ![]() Best runabout boats 20207/30/2023 ![]() ![]() Other features include a large enclosed head with a shower, wet bar with optional fridge, radar arch with integrated Bimini top and canvas attachment points, numerous removable tables and lounge seats, ample storage, and a magnificent swim deck. With 22 degrees of deadrise and total LOA of nearly 32ft, suffice it to say if the 290 BR cannot handle it, you probably don’t want to be out there anyway. The 2023 290 BR offered by Formula is a continuation of the performance-oriented family utility vessel that was begun almost 30 years ago - and it is arguably the best example. Bowrider versions of these so-called ‘Sun Sports’ soon followed and the big-water capable, self-bailing, twin-engined 30ft bowrider that dominates pleasure boating today was born. In the wake of its introduction, Sea Ray, Chaparral, Monterey, and others followed suit with their own similar offerings. Juxtaposed between a performance cruiser and a performance-oriented, go-fast design, the 280 SS had ample seating, a cabin that can sleep two, an enclosed head, and - most importantly - a low profile and up to 640hp of twin small block V8 power in a 28ft package. ![]() Although many bowriders may make adequate or even good fishing boats or tow boats respectively, their primary design purpose is to be a utility vessel that is good at everything but not specialised to suit any single on-water activity.įormula took the boating world by storm in the mid-90s with its revolutionary Sun Sport line, which was headlined by the introduction of the 1995 280 Sun Sport. Originally used as a term to denote a particular style of small, runabout boat with seating in the bow and a wraparound windshield with an opening section giving access to the aforementioned bow seating, many subsequent types of boats including deck boats, pontoon boats, power catamarans, and even center consoles, have since integrated bow seating into their designs, muddying the waters of what constitutes a true bowrider.įor the purposes of this article, a bowrider is defined as a recreational open bow pleasure boat of the runabout variety, not geared towards any particular niche like fishing, diving, or tow sports. Drew Maglio picks out 5 of the best bowriders ranging in price from $67,000 to $800,000… No boat type has changed more in the last 30 years than the aptly named bowrider. ![]() Take five result7/30/2023 ![]() ![]() While the non-residents of New York have to pay 30% federal tax.The winning prize consists of 9% state tax and 24% federal tax and the residents of New York have to pay an additional 4% municipal tax.The tax rate is different for residents of the States of New York and outsiders All the New York lottery prizes are based on tax, so no one will receive the advertised amount.In the Take 5 lottery game, only 50% of the revenue is suggested for the prize.The New York State Gaming Commission has the right to make any change in lottery rules.The first three prizes of the Take 5 lottery are pari-mutuel, which means that prizes may vary with the percentage of sales of tickets.The buyer is responsible for checking and analyzing all the data on the lottery ticket.The player must be 21 years of age to select the ticket through Quick Pick.Through Quick Pick QP, the computer will choose the numbers for the player. The competitors can select the numbers manually or they can use the Quick Pick QP option. The player has to select five numbers from 1 to 39.The participant can buy a ticket for the New York Take 5 lottery from any authorized retailer at the cost of $2.It is not necessary for a participant to be a resident of New York state, but it is mandatory for a player to be in the state at the time of drawing.The player must be 18 years of age or older than 18 years.The Take 5 New York lottery rules are straightforward and easy. ![]() NEW YORK TAKE 5 PAST WINNING NUMBERS Day & Date New York Take 5 Midday Results Today Monday 21 November 2022 New York Take 5 Evening Results Today Monday 21 November 2022 The Take 5 New York state lottery also provides a chance to play again if only one number matches with the drawn numbers in the next drawing. A participant can also get cash prizes if only three or four numbers on their tickets match the winning numbers. If all the selected numbers match the drawn numbers, then the competitor is definitely eligible for the jackpot. In the Take 5 New York lottery game, the participant has to select five numbers between 1 and 39. The drawings for the New York Take 5 lottery are to take place at 2:30 p.m. And now, the numbers for the lottery have been drawn twice daily since July 26, 2021. ![]() With the passage of time, Take 5 became popular among the people and became a daily played game at the beginning of 2000. The Take 5 New York lottery game first started in 1992 and was drawn only on Friday evenings. The Take 5 is one of the most exciting games played in the state of New York and allows players to win around $100,000. ![]() The velvet underground pale blue eyes7/30/2023 ![]() ![]() The song was also used in a scene of the 2008 film August, as well as 2009's Adventureland, the 2000 film The Vertical Ray of the Sun, and the 2015 film Regular Show: The Movie. The Kills recorded the song in 2010, releasing it as a B-side in early 2012 Īn instrumental version of the song was used in Julian Schnabel's 2007 film The Diving Bell and the Butterfly.Counting Crows covered the song several times at live shows in 2003 and later.Alejandro Escovedo includes a live cover of the song-a duet with Kelly Hogan-on his 1999 release Bourbonitis Blues.The recording eventually ended up on the band's first EP, Ask for It (1995). Hole's version included lyrically altered verses but retained the chorus lyrics and chord progression. Hole covered the song live at the Whisky a Go Go in February 1992, and frontwoman Courtney Love introduced it as "the original new waver".Marisa Monte has a cover of the song on her 1994 album Verde, Anil, Amarelo, Cor de Rosa e Carvão (a.k.a.Central Rain", released in 1984 and collected on their 1987 album Dead Letter Office. covered the song for the B-side of the single of " So. Edwyn Collins recorded the song with Paul Quinn and released it as a single in 1984.Patti Smith performed the song live in the mid- to late-1970s."Pale Blue Eyes" has been covered by a number of artists in addition to Lou Reed and Maureen Tucker from Velvet Underground: Sterling Morrison – electric guitar, backing vocals. ![]() Doug Yule – bass, Hammond organ, backing vocals.Lou Reed – lead vocals, electric guitar. ![]() The song is said to have been inspired by Shelley Albin, Reed's first love, who at the time was married to another man. It was included on the band's 1969 album The Velvet Underground.ĭespite the name, "Pale Blue Eyes" was written about someone whose eyes were hazel, as Reed notes in his book Between Thought and Expression. He recorded a demo with John Cale in May 1965. " Pale Blue Eyes" is a song written and sung by Lou Reed and performed by The Velvet Underground. ![]() Showoff fail compilation7/30/2023 ![]() ![]() ![]() This tendency to socialize is frequently retained in captive populations. ![]() The Panda Moor Goldfish is a social species that travel in wild groups. This species is known for its peaceful and social nature. The behavior of the Panda Moor Goldfish is one of its most fascinating and endearing characteristics. Female Panda Moor Goldfish, on the other hand, tend to be plumper in the abdominal area, especially during breeding season when they are bursting at the seams with eggs. During the breeding season, males may have breeding tubercles, which are small white bumps on the gill covers and fins. Male Panda Moor Goldfish have more pronounced and thicker dorsal and anal fins, which they use to attract a female mate during breeding. Some subtle differences can assist pet fish owners in determining the gender of their fish. The gender of a Panda Moor Goldfish is not always easily distinguishable, as male and female fish of this species can look very similar in appearance. Pet fish owners must remember that the Panda Moor Goldfish is a slow-growing species that can take several years to mature. However, it is important to note that the size of the Panda Moor Goldfish can vary greatly depending on various factors such as diet, water quality, and living conditions. When fully mature, this species can grow as long as 8 inches or more, making it one of the larger goldfish species. The size of the Panda Moor Goldfish is one of its most notable characteristics, as it can grow quite large in captivity. The body is typically a dull white or yellow, contrasting sharply with the black markings. It has a large, distinct head with a prominent forehead and small, almond-shaped eyes. The Panda Moor Goldfish is a plump, full-bodied species with a round body. The fins are also important for the fish’s overall health and well-being because they aid in balance and maneuvering in the water. This species’ fins are long, flowing, and delicate, giving it a graceful and beautiful appearance while swimming. The Panda Moor Goldfish is known for its elegant and flowing fins, in addition to its markings. These markings lend the Panda Moor Goldfish a distinct, panda-like appearance that is both appealing and endearing. Black markings are found on the head, back, and tail, while white markings are found on the belly and fins. As its name suggests, this fish is distinguished by its black and white markings, arranged in a distinct pattern on its body and fins. The Panda Moor Goldfish’s appearance makes it stand out from other goldfish species. The species is now widely available in pet shops and on the internet. The Panda Moor Goldfish spread to other countries and has become a popular choice for home aquariums worldwide. Selective breeding of goldfish species, including the telescope and the lionhead goldfish, produced the breed.Ī tough and attractive species quickly became popular among pet fish owners. The origin of the Panda Moor Goldfish can be traced back to China, where it was first bred and developed. ![]() AuthorWrite something about yourself. No need to be fancy, just an overview. ArchivesCategories |